- Title
- CO₂ quality control in oxy-fuel technology for CCS: SO₂ removal by the caustic scrubber in Callide Oxy-fuel Project
- Creator
- Liu, Dunyu; Wall, Terry; Stanger, Rohan
- Relation
- International Journal of Greenhouse Gas Control Vol. 51, Issue August 2016, p. 207-217
- Publisher Link
- http://dx.doi.org/10.1016/j.ijggc.2016.05.026
- Publisher
- Elsevier
- Resource Type
- journal article
- Date
- 2016
- Description
- Flue gas from Oxy-fuel combustion is enriched with CO₂ and SO₂. SO₂ has significant impacts throughout the system. This paper primarily focuses on the operation characteristics of caustic scrubber for the removal of SO₂ in Callide Oxy-fuel Project. Both gas and liquid sampling and analysis were carried out for the caustic scrubber which comprises two spray columns, the initial Quencher followed by the low pressure (LP) scrubber. Dynamic changes of gas and liquid species in two scrubbers have been obtained and several conclusions can be drawn. From gas analysis, it can be concluded that the Quencher had high capture efficiencies for SO₂ (97%) and NO₂ (77%), and low capture efficiencies for NO (32%). The Quencher captured most of the SO₂ and NO₂; the LP scrubber captured a limited amount of SO₂ (1%) and NO₂ (4%). Therefore, the LP scrubber is not a necessary component for capturing SO₂. Liquid analysis gave consistent results with gas analysis in that the Quencher (0.011–0.037 M) contained a 100 times higher concentration of Total S than that (0.0001–0.0006 M) in the LP scrubber. The Total S existed in the form of S(IV) and S(VI) in the Quencher, and only in the form of S(VI) in the LP scrubber. The S(VI) ratio of 11% in the Quencher agreed with the reported 2–15% oxidation. SO₂ concentration in gas phase can be correlated well with Total S in liquid, but not the effective ratio of Na⁺. Mass balance between gas and liquid Total S can be achieved. The long term storage of liquid samples is accompanied by pH changes and desorption of CO₂ with exposure to the atmosphere. The final pH depends on the presence of HCO₃⁻. In the presence of HCO₃⁻ in liquids, the final pH is around 8; in the absence of HCO₃⁻, the final pH is around 4. The increase in pH to 8 is explained by desorption of CO₂. The amount of CO₂ desorbed is around 0.0614% of the amount of CO₂ in the CPU.
- Subject
- CO₂ quality control; oxy-fuel; SO₂ removal; caustic scrubber
- Identifier
- http://hdl.handle.net/1959.13/1331227
- Identifier
- uon:26572
- Identifier
- ISSN:1750-5836
- Language
- eng
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